Development of metrological support for quantitative NMR analyzers
https://doi.org/10.20915/2077-1177-2018-14-1-2-39-48
Abstract
The first part of the article presents the history of creating quantitative NMR analyzers of oil content and humidity of oil crop seeds and their by-products. The developed NMR analyzers differ from similar devices in the availability of metrological support (reference materials (RMs) of approved type) and an extended range of moisture measurement (5–20)%. The main metrological characteristics of the developed NMR analyzer are given. The second part of the article deals with problems solved in the process of carrying out the scientific research work on the development of metrological support for quantitative NMR analyzers. Based on the tasks set, the most optimal substances imitating oil and water components contained in the oil crops and their by-products were selected. The imitation substances in question provide long-term stability of the developed RMs, erewhile being chemically inert to each other, environmentally safe? and allowing an imitation of oil and water in oil crops and their by-products. Organosilicon fluids with (35–40) ms and (95–130) spin-spin relaxation times of protons ms are proposed as an oil imitator. To imitate water, a one-component self-vulcanizing organosilicon compound, which is applied to paper strips with a thin coat, is used in the developed type-approved RMs. In conclusion, the article presents perspective directions of developing RMs of mass fraction imitators of typical fatty acids in the oil of oil crops (sunflower, linseed, and rapeseed).
About the Authors
S. M. Prudnikov
Federal State Budgetary Scientific Institution «National Research Institute of Oil Crops n. a. V. S. Pustovoit»
Russian Federation
Russian Federation
Sergey M. Prudnikov – D. Sc. (Eng.), Professor, Head of the Department of Physical Methods of Research
17 Filatova St., Krasnodar, 350038
B. Ya. Vityuk
Federal State Budgetary Scientific Institution «National Research Institute of Oil Crops n. a. V. S. Pustovoit»
Russian Federation
Russian Federation
Boris Ya. Vityuk – Ph.D (Eng.), Lead Engineer at the Department of Physical Methods of Research
17 Filatova St., Krasnodar, 350038
O. S. Agafonov
Federal State Budgetary Scientific Institution «National Research Institute of Oil Crops n. a. V. S. Pustovoit»
Russian Federation
Russian Federation
Oleg S. Agafonov – Ph.D (Eng.), Senior Researcher at the Department of Physical Methods of Research
17 Filatova St., Krasnodar, 350038
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Review
For citations:
Prudnikov S.M., Vityuk B.Ya., Agafonov O.S. Development of metrological support for quantitative NMR analyzers. Measurement Standards. Reference Materials. 2018;14(1-2):39-48. (In Russ.) https://doi.org/10.20915/2077-1177-2018-14-1-2-39-48
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