Certified Reference Materials of Alkyl Carbonates and Multicomponent Solution of Alkyl Carbonates
https://doi.org/10.20915/2077-1177-2025-21-2-31-44
Abstract
The article presents information on the development of new types of certified reference materials (СRMs) for the composition of individual alkyl carbonates and СRM for the composition of a multicomponent solution of alkyl carbonates in methanol, provided with metrological traceability to GET 208-2024. A description of the procedure for preparation and certification of СRMs is provided, including studies of material homogeneity and stability. The features of certification of a multicomponent solution of organic substances of the same homologous series are described. The certified characteristic of СRMs for the composition of alkyl carbonates is the mass fraction of the main component in the pure substance (from 99.54 to 99.97 %) with a relative expanded uncertainty not exceeding 0.25 %. The certified characteristic of СRM for the composition of a multicomponent solution is the mass concentration of individual alkyl carbonates in methanol (from 1.99 to 2.01 mg/cm3) with a relative expanded uncertainty of certified values of 1.5 %.
Keywords
About the Authors
A. I. KrylovRussian Federation
Anatoliy I. Krylov, Dr. Sci. (Chem.), Department Head
Department of State Measurement Standards in the field of Organic and Inorganic
190005; 19 Moskovskiy ave.; St. Petersburg
A. Yu. Miheeva
Russian Federation
Alena Yu. Miheeva, Cand. Sci. (Chem.), Deputy Head of the Department
Department of State Measurement Standards in the field of Organic and Inorganic Analysis
190005; 19 Moskovskiy ave.; St. Petersburg
S. V. Spirin
Russian Federation
Sergey V. Spirin, Acting Head of the Laboratory
Research Department of State Standards in the field of Organic and Inorganic Analysis; Laboratory of Organic Analysis
190005; 19 Moskovsky ave.; St. Petersburg
A. G. Budko
Russian Federation
Aleksandra G. Budko, Researcher
Department of State Measurement Standards in the field of Organic and Inorganic Analysis
190005; 19 Moskovskiy ave.; St. Petersburg
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Review
For citations:
Krylov A.I., Miheeva A.Yu., Spirin S.V., Budko A.G. Certified Reference Materials of Alkyl Carbonates and Multicomponent Solution of Alkyl Carbonates. Measurement Standards. Reference Materials. 2025;21(2):31-44. (In Russ.) https://doi.org/10.20915/2077-1177-2025-21-2-31-44

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