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Certified Reference Materials of Alkyl Carbonates and Multicomponent Solution of Alkyl Carbonates

https://doi.org/10.20915/2077-1177-2025-21-2-31-44

Abstract

   The article presents information on the development of new types of certified reference materials (СRMs) for the composition of individual alkyl carbonates and СRM for the composition of a multicomponent solution of alkyl carbonates in methanol, provided with metrological traceability to GET 208-2024. A description of the procedure for preparation and certification of СRMs is provided, including studies of material homogeneity and stability. The features of certification of a multicomponent solution of organic substances of the same homologous series are described. The certified characteristic of СRMs for the composition of alkyl carbonates is the mass fraction of the main component in the pure substance (from 99.54 to 99.97 %) with a relative expanded uncertainty not exceeding 0.25 %. The certified characteristic of СRM for the composition of a multicomponent solution is the mass concentration of individual alkyl carbonates in methanol (from 1.99 to 2.01 mg/cm3) with a relative expanded uncertainty of certified values of 1.5 %.

About the Authors

A. I. Krylov
D. I. Mendeleyev Institute for Metrology
Russian Federation

Anatoliy I. Krylov, Dr. Sci. (Chem.), Department Head

Department of State Measurement Standards in the field of Organic and Inorganic

190005; 19 Moskovskiy ave.; St. Petersburg



A. Yu. Miheeva
D. I. Mendeleyev Institute for Metrology
Russian Federation

Alena Yu. Miheeva, Cand. Sci. (Chem.), Deputy Head of the Department

Department of State Measurement Standards in the field of Organic and Inorganic Analysis

190005; 19 Moskovskiy ave.; St. Petersburg



S. V. Spirin
D. I. Mendeleyev Institute for Metrology
Russian Federation

Sergey V. Spirin, Acting Head of the Laboratory

Research Department of State Standards in the field of Organic and Inorganic Analysis; Laboratory of Organic Analysis

190005; 19 Moskovsky ave.; St. Petersburg



A. G. Budko
D. I. Mendeleyev Institute for Metrology
Russian Federation

Aleksandra G. Budko, Researcher

Department of State Measurement Standards in the field of Organic and Inorganic Analysis

190005; 19 Moskovskiy ave.; St. Petersburg



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Review

For citations:


Krylov A.I., Miheeva A.Yu., Spirin S.V., Budko A.G. Certified Reference Materials of Alkyl Carbonates and Multicomponent Solution of Alkyl Carbonates. Measurement Standards. Reference Materials. 2025;21(2):31-44. (In Russ.) https://doi.org/10.20915/2077-1177-2025-21-2-31-44

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