Bismuth Determination by Controlled-Potential Coulometry: Developing a Highly Accurate Procedure based on GET 176
https://doi.org/10.20915/2077-1177-2023-19-4-129-141
Abstract
In this work, we develop a procedure for reproducing the units of bismuth mass fraction in metallic bismuth and those of bismuth (III) mass concentration in bismuth nitrate solutions by controlled-potential coulometry based on the GET 176-2019 State primary standard of mass (molar, atomic) fraction units and mass (molar) concentration of components in liquid and solid substances and materials based on coulometry. The results obtained can be used when manufacturing certified reference materials (CRMs) for the composition of high-purity bismuth and CRMs for the composition of solutions of bismuth (III) ions directly traceable to GET 176-2019. These CRMs may find application in pharmacological, metallurgical, and nuclear industries.
Keywords
State primary standard,
GET 176,
certified reference material,
CRM,
controlled-potential coulometry,
mass fraction,
bismuth,
traceability,
standard uncertainty,
bismuth mass concentration
Supporting agencies: The research was performed within the framework of the research theme «Development, improvement, and maintenance of the state primary measurement standards, as well as development and improvement of the state primary reference measurement procedures (methods)». All measurements were performed using the facilities of UNIIM, a branch of D. I. Mendeleyev All-Russian Institute for Metrology.
About the Authors
V. M. Zyskin
UNIIM – Affiliated Branch of the D. I. Mendeleyev Institute for Metrology
Russian Federation
Russian Federation
Veniamin M. Zyskin – Leading Engineer, the Laboratory of Physical and Chemical Methods for Metrological Certification of Reference Materials
4 Krasnoarmeyskaya str., Yekaterinburg, 620075
A. В. Sobina
UNIIM – Affiliated Branch of the D. I. Mendeleyev Institute for Metrology
Russian Federation
Russian Federation
Alena V. Sobina – Cand. Sci. (Eng.), Head of the Laboratory of Physical and Chemical Methods for Metrological Certification of Reference Materials
4 Krasnoarmeyskaya str., Yekaterinburg, 620075
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Review
For citations:
Zyskin V.M., Sobina A.В. Bismuth Determination by Controlled-Potential Coulometry: Developing a Highly Accurate Procedure based on GET 176. Measurement Standards. Reference Materials. 2023;19(4):129-141. (In Russ.) https://doi.org/10.20915/2077-1177-2023-19-4-129-141
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