Application of a number of physical and chemical analysis methods the assessment of a multicomponent sample composition of natural water
https://doi.org/10.20915/2687-0886-2020-16-2-41-55
Abstract
The authors present experimental data on the development of a special sample in the form of a dispersed material that simulates the mineral macro-component composition of natural surface water. The results of the study obtained by a number of physico-chemical analysis methods were compared to determine the mass concentration of the micro-component - manganese (II) in the sample. Determination of the mass concentration of manganese (II) was carried out by the methods of spectrophotometry for PND F 14.1:2.61, x-ray fluorometry for PND F 14.1:2:4.130, inversion voltammetry for PND F 14.1:24.217.Procedures for establishing the metrological characteristics of a special sample to control the accuracy of the results of measurements of the mass concentration of manganese (II) using a number of physicо-chemical analysis methods have been carried out.A number of advantages and disadvantages of certified measurement methods that are widely used in chemical laboratories for determining the content of manganese in natural surface water are noted. The necessity of carrying out the procedure of certification of the spectrophotometric method with the use of manganese (II) ions - sodium periodate as an oxidizer is shown.
About the Authors
L. V. Trubacheva
Udmurt State University
Russian Federation
Russian Federation
Larisa. V. Trubacheva – PhD (Chemical), associate professor, head of the department of fundamental and applied chemistry, 1 Universitetskaya str., Izhevsk, 426034, Russian Federation
S. Yu. Lohaninа
Udmurt State University
Russian Federation
Russian Federation
Svetlana Yu. Lohaninа – PhD (Engineering), associate professor, head of the department of fundamental and applied chemistry, 1 Universitetskaya str., Izhevsk, 426034, Russian Federation
T. I. Belova
Udmurt State University
Russian Federation
Russian Federation
Tat’iana I. Belova – engineer central ecological laboratory of chemical analysis, department of fundamental and applied chemistry, 1 Universitetskaya str., Izhevsk, 426034, Russian Federation
References
1. GOST ISO/IEC17025–2019 General requirements for the competence of testing and calibration laboratories. Moscow, Standartinform, 2019, 32 p. (In Russ.).
2. Medvedevskikh M. Y., Baranovskaja V. B. Proficiency testing and other interlaboratory comparisons. EURACHEM leaflet. Reference materials. 2017;13(3–4):41–44. (In Russ.).
3. Gorjaeva L. I., Lebedeva E. L. Development of certified reference material of mineral composition of natural water designed to control of turbidity measurement accuracy. Reference materials. 2017;13(1):27–36. DOI: 10.20915/2077-1177-2017-13-1-27-36
4. Kipphardt H., Matschat R., Vogl J., Gusarova T., Czerwensky M., Heinrich H. J., Hioki A., Konopelko L. A., Methven B., Miura T. et al. Purity determination as needed for the realization of primary standards for elemental determination–status of international comparability. Accred Qual Assur. 2010;15(1):29–37. DOI: 10.1007/s00769-009-0557-0
5. SO Guide 35:2017 Reference materials – guidance for characterization and assessment of homogeneity and stability.
6. ISO Guide 34–2009 General requirements for competence of reference material producers.
7. Atanov A. N., Boldina O. V., Gagarin S. V., Propisnova V. A., Sidorov L. S. Standartnye obraztsy v obespechenii proslezhivaemosti rezul’tatov izmerenii pokazatelei kachestva i bezopasnosti vody [Reference materials in providing traceability of measurement results quality indicators and water safety]. Kontrol’ kachestva produktsii. 2017;(4);39–46. (In Russ.).
8. Isaev M. A., Golovkov I. G., Iurk S. A. Rodnikovye i artezianskie vody Izhevska [Spring and artesian waters of Izhevsk]. Izhevsk, publishing house «Secrets of beauty and health», 2004. 109 p.
9. Brown R. J. C., Milton M. J. T. Development in accurate and traceable chemical measurements. Chemical Society Reviews. 2008;(36);904–913. (In Russ.).
10. Vasileva I. E., Shabanova E. V. The role and prospects of development of certified reference materials of chemical composition of natural and man-made environments in geoanalysis. Reference materials. 2016;(2):16–35. DOI: 10.20915/2077-1177-2016-0-2-16-35. (In Russ.).
11. Osintseva E. V. Commutability evaluation of reference materials of composition and properties of substances and materials. Reference materials. 2016;(3):61–68. DOI: 10.20915/2077-1177-2016-0-3-61-68. (In Russ.).
12. Dombrovskaya M. A., Lisienko D. G., Kubrina E. D. Creating procedures for determining the content of main components in reagents used for synthesizing certified reference materials for composition. Reference materials. 2017;13(2):27–36. DOI: 10.20915/10.20915/2077-1177-2017-13-2-27-36. (In Russ.).
13. Voida A., Matveev A., Ezhak B. Desiat’ bar’erov na puti standartnykh obraztsov [Ten barriers to reference materials]. Kontrol’ kachestva produktsii. 2018;(6);44–48. (In Russ.).
14. Voida A., Matveev A., Ezhak B. Problemy distributsii standartnykh obraztsov khimicheskogo sostava veshchestv i materialov [Problems of distribution of standard samples of the chemical composition of substances and materials], Kontrol’ kachestva produktsii. 2017;(11);5–8. (In Russ.).
15. O sostoianii sanitarno-epidemiologicheskogo blagopoluchiia naseleniia v Udmurtskoi Respublike v 2018 godu: Gosudarstvennyi doklad – Upravlenie Federal’noi sluzhby po nadzoru v sfere zashchity prav potrebitelei i blagopoluchiia cheloveka po Udmurtskoi Respublike [On the state of sanitary and epidemiological welfare of the population in the Udmurt Republic in 2018: State report-Department of the Federal service for supervision of consumer rights protection and human welfare in the Udmurt Republic]. 2019. 180 p. (In Russ.).
16. GOST 10398–76 Reagents and super pure substances. Complexonometric method for determination of basic matter content. Moscow, Standartinform, 2002, 15 p. (In Russ.)
17. Kristian G. Analiticheskaia khimiia [Analytical chemistry]: In 2 vol. (G. Christian translation from English). Moscow, BINOM. Knowledge lab, 2012. (In Russ.).
18. Analiticheskaia khimiia. Problemy i podkhody [Analytical chemistry. Problems and approaches]: In 2 vol. R. Kelner, J.-M. Mermet, M. Otto, M. Widmer (ed.). Moscow, Mir: LLC «Publishing house AST», 2004. (In Russ.).
19. Leo M. L. Nollet, Lin S. P. Degeler Analiz vody. Spravochnik [Analysis of water. Reference]: translated from English. (G). I. V. Vasilyeva, E. L. Proletarskaya translation from English). St. Petersburg, TSOP «Profession». 2012. 920 p. (In Russ.).
20. Khodakovskaya I. V., Popkova G. N., Bazianova V. V. Comparison of methods for certification of stannic, stibium and lead traces in reference materials for steel. Reference materials. 2016;(3):32–37. DOI: 10.20915/2077-1177-2016-0-3-32-37. (In Russ.).
21. Moskvin L. N. (ed.). Analiticheskaia khimiia. Metody identifikatsii i opredeleniia veshchestv [Analytical chemistry. Methods of identification and determination of substances].). St. Petersburg, LAN publishing House. 2019. 587 p. (In Russ.).
22. PND f 14.1:2:4.217–06 Method of measurement of mass concentration of manganese by the method of IVA for the instrument type THAT. Tomsk, 2006. 21 p. (In Russ.).
23. Pupyshev A. A. Atomno-absorbtsionnyi spektral’nyi analiz [Atomic absorption spectrum analysis]. Moscow, Technosphere. 2009. 784 p. (In Russ.).
24. Komissarenko A. A, Andreev S. B. Rentgenofluorestsentyi metod analiza: metodicheskie ukazaniia k laboratornym rabotam [x-ray Fluorescence method of analysis: guidelines for laboratory work]. St. Petersburg, GOU VPO «Saint Petersburg state technological University of plant polymers», 2008. 36 p. (In Russ.).
25. PND F 14.1: 2: 4.130–98 Method of measuring the mass concentration of vanadium, bismuth, iron, cobalt, manganese, copper, Nickel, lead, chromium, zinc in drinking, natural and waste water by x-ray fluorescence method after concentration on cellulose DETATE filters (FR.1.31.2011.09284). St. Petersburg: LLC «NPO «SPECTRON», 2009. 17 p. (In Russ.).
26. GOST 31870–2012 Drinking water. Determination of elements content by atomic spectrometry methods. Moscow, Standartinform, 2013, 18 p. (In Russ.),
27. PND F 14.1:2.61–96 Measuring the mass concentration of Mn2+ in natural and waste waters by photometric method with the use of ammonium persulfate. Moscow, FBU «FCO», 2004, 16 p. (In Russ.).
28. GOST 4974–2014 Drinking water. Determination of manganese content by photometric methods. Moscow, Standardinform, 2015. 15 p. (In Russ.).
29. Rabinovich V. A., Khavin Z. Ia. Kratkii khimicheskii spravochnik [Short chemical Handbook], A. A. Potekhin and A. I. Efimova (eds.). Leningrad, Chemistry, 1991. 432 p. (In Russ.).
30. PND F 14.1:2: 4.111–97 Quantitative chemical analysis of water. Methods of measuring the mass concentration of chloride ions in drinking, surface and waste water by mercurimetric method. Moscow, State Standard Of Russia, 2011. 20 p. (In Russ.).
31. PND F 14.1:2: 4.4–95 Quantitative chemical analysis of water. Method of measuring the mass concentration of nitrate ions in drinking, surface and waste water by photometric method with salicylic acid. Moscow, State Standard Of Russia, 2011. 13 p. (In Russ.).
32. PND F 14.1:2:3:4.121–97 Quantitative chemical analysis of waters. Technique of pH measurements in water by potentiometric method. Moscow, State Standard Of Russia, 2004. 16 p. (In Russ.).
33. GOST 31957–2012 Water. Methods for determination of alkalinity and mass concentration of carbonates and hydrocarbonates. Moscow, Standardinform, 2013. 25 p. (In Russ.).
34. R50.2.058-2007 GSI Assessment of uncertainties of certified values of standard samples. Moscow, Standardinform, 2008. 28 p. (In Russ.).
35. GOST 8.531-2002 State system for ensuring the uniformity of measurements. Reference materials of composition of solid and disperse materials. Ways of homogeneity assessment. Moscow, Standardinform, 2002. 12 p. (In Russ.).
36. Osintseva E. V. GOST 8.315 «GSI. Reference materials of composition and properties of substances and materials. Basic concepts»: basic principles of revision. Reference materials. 2016;(4):15–24. (In Russ.).
37. Tereshchenko A. G. Vnutrilaboratornyi kontrol’ kachestva rezul’tatov khimicheskogo analiza [Intra-Laboratory quality control of chemical analysis results]. Tomsk, STT, 2017. 266 p. (In Russ.).
Review
For citations:
Trubacheva L.V., Lohaninа S.Yu., Belova T.I. Application of a number of physical and chemical analysis methods the assessment of a multicomponent sample composition of natural water. Measurement Standards. Reference Materials. 2020;16(2):41-56. (In Russ.) https://doi.org/10.20915/2687-0886-2020-16-2-41-55
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