rmjournalЭталоны. Стандартные образцыMeasurement Standards. Reference Materials2687-0886D. I. Mendeleyev Institute for Metrology10.20915/2077-1177-2023-19-4-129-141rmjournal-427Research ArticleСовременные методы анализа веществ и материаловModern methods of analysis of substances and materialsОпределение висмута методом прямой кулонометрии с контролируемым потенциалом: разработка высокоточной методики с применением ГЭТ 176Bismuth Determination by Controlled-Potential Coulometry: Developing a Highly Accurate Procedure based on GET 176ЗыскинВ. М.ZyskinV. M.

Зыскин Вениамин Михайлович – старший научный сотрудник лаборатории физических и химических методов метрологической аттестации стандартных образцов 

620075, г. Екатеринбург, ул. Красноармейская, 4

Veniamin M. Zyskin – Leading Engineer, the Laboratory of Physical and Chemical Methods for Metrological Certification of Reference Materials

4 Krasnoarmeyskaya str., Yekaterinburg, 620075

zuskinvm@uniim.ruhttps://orcid.org/0000-0002-5873-7326СобинаА. В.SobinaA. В.

Собина Алена Вячеславовна – канд. тех. наук, заведующий лабораторией физических и химических методов метрологической аттестации стандартных образцов 

620075, г. Екатеринбург, ул. Красноармейская, 4

Alena V. Sobina – Cand. Sci. (Eng.), Head of the Laboratory of Physical and Chemical Methods for Metrological Certification of Reference Materials

4 Krasnoarmeyskaya str., Yekaterinburg, 620075

SobinaAV@uniim.ruУНИИМ – филиал ФГУП «ВНИИМ им. Д. И. Менделеева»РоссияUNIIM – Affiliated Branch of the D. I. Mendeleyev Institute for MetrologyRussian Federation202325092023194129141Copyright © Зыскин В.М., Собина А.В., 20232023Зыскин В.М., Собина А.В.Zyskin V.M., Sobina A.В.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://www.rmjournal.ru/jour/article/view/427

В статье представлены результаты исследований по разработке методики воспроизведения единиц массовой доли висмута в металлическом висмуте и массовой концентрации висмута (III) в растворах висмута азотнокислого методом кулонометрии с контролируемым потенциалом на Государственном первичном эталоне единиц массовой (молярной, атомной) доли и массовой (молярной) концентрации компонентов в жидких и твердых веществах и материалах на основе кулонометрии ГЭТ 176-2019.

Результаты работ могут быть использованы для производства стандартного образца состава висмута высокой чистоты и стандартного образца состава растворов ионов висмута (III) с прямой прослеживаемостью к ГЭТ 176-2019 для фармакопеи, металлургической и атомной промышленности.

In this work, we develop a procedure for reproducing the units of bismuth mass fraction in metallic bismuth and those of bismuth (III) mass concentration in bismuth nitrate solutions by controlled-potential coulometry based on the GET 176-2019 State primary standard of mass (molar, atomic) fraction units and mass (molar) concentration of components in liquid and solid substances and materials based on coulometry. The results obtained can be used when manufacturing certified reference materials (CRMs) for the composition of high-purity bismuth and CRMs for the composition of solutions of bismuth (III) ions directly traceable to GET 176-2019. These CRMs may find application in pharmacological, metallurgical, and nuclear industries.

Государственный первичный эталонГЭТ 176стандартный образецкулонометрия с контролируемым потенциаломмассовая долявисмутпрослеживаемостьстандартная неопределенностьмассовая концентрация висмутаState primary standardGET 176certified reference materialCRMcontrolled-potential coulometrymass fractionbismuthtraceabilitystandard uncertaintybismuth mass concentrationИсследование выполнено в рамках работ по теме «Разработка, совершенствование, содержание государственных первичных эталонов единиц величин, а также разработка и совершенствование государственных первичных референтных методик (методов) измерений». Все измерения проводились с использованием оборудования УНИИМ – филиала ФГУП «ВНИИМ им. Д. И. Менделеева».The research was performed within the framework of the research theme «Development, improvement, and maintenance of the state primary measurement standards, as well as development and improvement of the state primary reference measurement procedures (methods)». 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The authors declare that there are no conflicts of interest present.